york mulberry outlet Aromatic hydrocarbons

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Aromatic hydrocarbons (also called arenes) are a class of cyclic hydrocarbons with complete conjugation (which often means alternating double and single bonds) in the molecular rings. They tend to be more stable than normal alkenes. Not all fully conjugated cyclic hydrocarbons are aromatic, however some act like normal alkenes, and one (cyclobutadiene) is anti aromatic, and is even less stable than a normal alkene. The reasons for this are discussed below, under theoretical considerations. The most common aromatic hydrocarbon is benzene, which was also the first to be discovered. Many larger aromatics consist of multiple benzene rings fused together. Benzene, alkyl benzenes (such as toluene), and fused ring aromatics (such as anthracene) can all be isolated from coal tar. There are also aromatic compounds with chemical elements other than carbon and hydrogen, so they are aromatic but not hydrocarbons. crude oil from the ground. Other sources include coal tar. BTX refers to a mixture of Benzene, Toluene, and three types or isomers of Xylenes. Such arene mixtures often have Ethylbenzene also. Compounds from this sort of mixture can be added to gasoline to increase octane number. Benzene can be methylated (an H changed to CH3 group) once to give toluene or twice to give a xylene. Benzene can also react with ethylene to give ethylbenzene,
york mulberry outlet Aromatic hydrocarbons
which in turn can give styrene and hydrogen ( Styrene is commonly used as a monomer for polymerization to polystyrene, sometimes with some divinylbenzene for cross linking, to a styrene butadiene copolymer, or ABS, an acrylonitrile butadiene styrene copolymer.

The three isomers of xylene are ortho , meta , and para xylene. There can be isomerization units to interconvert xylenes in a mixture to an equilibrium mixture of the three isomers. There are separation methods to separate the xylenes. The para xylene is the most desired because it can be oxidized to terephthalic acid which is then polymerized to the very useful plastic polyethylene terephthalate.

A cumene process has been used to convert cumene (isopropylbenzene) to phenol and acetone.

While aromatic hydrocarbons appear to contain multiple double bonds, they undergo none of the reactions typical of alkenes. Catalytic addition of hydrogen to aromatics requires either higher pressures of hydrogen or more powerful catalysts than does addition to alkenes. Water will add to alkenes with acid catalysis, but will not add to aromatic rings. Some larger aromatic rings will undergo reactions more typical of alkenes. One of those that will is the middle ring of anthracene.

In general,electrophiles replace a hydrogen atom of an aromatic ring instead of adding to the double bonds. The most common reactions include:A mixture of nitric and sulfuric acids is used to replace a hydrogen atom with a nitro ( NO2) group. These sulfonic acids are used to make sulfa drugs, and are also strong acids soluble in organic solvents (unlike some of the strong mineral acids)This process uses a carboxylic acid chloride and AlCl3 to introduce an acyl group,
york mulberry outlet Aromatic hydrocarbons
which forms a benzyl ketone.